Detecting ‘Spectral Fingerprints’ Of Atoms & Molecules Beyond Our Solar System

An international collaboration of astronomers led by Queen’s University Belfast has discovered a new chemical signature in the atmosphere of an extrasolar planet, a planet that orbits a star other than the sun.

The lead researcher based at the ABC and the School of Mathematics and Physics at Queen’s University Belfast, Dr Stevanus Nugroho, said:

“The discovery is the first direct evidence of OH in the atmosphere of a planet beyond the Solar System. It shows not only that astronomers can detect this molecule in exoplanet atmospheres, but also that they can now begin to understand the detailed chemistry of this planetary population.”

Such advances are important if, in the future, we ever want to probe atmospheres of smaller rocky planets that resemble the Earth.

Using the high-powered Subaru Telescope, the hydroxyl radical (OH), one of the most dominant oxygen-bearing molecules at high temperature, was found in the dayside of the exoplanet named WASP-33b.

Dr Neale Gibson, assistant professor at Trinity College Dublin explained:

“The science of extrasolar planets is relatively new, and a key goal of modern astronomy is to explore these planets’ atmospheres in detail and eventually to search for ‘Earth-like’ exoplanets – planets similar to our own.

“Every new atmospheric species discovered further improves our understanding of exoplanets and the techniques required to study their atmospheres and takes us closer to this goal.”


In the Earth’s atmosphere, OH is mainly produced by the reaction of water vapour with atomic oxygen.

It is a so-called ‘atmospheric detergent’ and plays a crucial role in the Earth’s atmosphere to purge pollutant gasses that can be dangerous to life, such as methane and carbon monoxide.

In a much hotter and bigger planet like WASP-33b (where astronomers have previously detected signs of iron and titanium oxide gas) OH plays a key role in determining the chemistry of the atmosphere through interaction with water vapour and carbon monoxide.

Most of the OH in the atmosphere of WASP-33b is thought to be produced by the destruction of water vapour due to the extremely high temperature.

Dr Ernst de Mooij, from the School of Mathematics and Physics at Queen’s University Belfast, said:

“We see only a tentative and weak signal from water vapour in our data, which would support the idea that the water is destroyed to form hydroxyl in this extreme environment.”

To make this discovery, the team used the InfraRed Doppler (IRD) instrument and the Subaru Telescope located in the summit area of Maunakea in Hawai`i (about 4,200 m above sea level).

Professor Motohide Tamura, one of the principal investigators of IRD, Director of Astrobiology Center, said:

“IRD is the best instrument to study the atmosphere of an exoplanet in the infrared.”

This new instrument can detect the ‘spectral fingerprints’ of atoms and molecules – a unique set of dark absorption features superimposed on the rainbow of colours (or spectrum) that are emitted by stars and planets.

As the planet orbits its host star, its velocity relative to the Earth changes with time. And much like the siren of an ambulance or the roar of a racing car’s engine changes pitch while speeding past us, the frequencies of light of these spectral fingerprints changes with the velocity of the planet. This allowed the researchers to separate the planet’s signal from its bright host star, which normally overwhelms such observations, despite modern telescopes being nowhere near powerful enough to take images of such ‘hot Jupiter’ exoplanets.

And the future?

Dr Hajime Kawahara, assistant professor at the University of Tokyo added:

“These techniques for atmospheric characterization of exoplanets are still only applicable to very hot planets, but we would like to further develop instruments and techniques that enable us to apply these methods to cooler planets, and ultimately, to a second Earth.” 

Professor Chris Watson, head of the Exoplanet Group within the Astrophysics Research Centre at the School of Mathematics and Physics at Queen’s University Belfast, explained:

“While WASP-33b may be a giant planet, these observations are the testbed for the next-generation facilities like the Thirty Meter Telescope and the European Extremely Large Telescope in searching for biosignatures on smaller and potentially rocky worlds, which might provide hints to one of the oldest questions of humankind, ‘Are we alone?’”

The research was funded by UK Science Technology and Facility Council grant ST/P000312/1.

The results have been published in the Astrophysical Journal Letters and involved researchers from Queen’s University Belfast, the Astrobiology Center (ABC) of the National Institutes of Natural Sciences in Tokyo, and Trinity College Dublin.

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